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Patulin Adsorption Kinetics on Activated Carbon, Activation Energy and Heat of Adsorption
Authors:MEHMET MUTLU  NILÜFER HIZARCIO&#;LU  VURAL GÖKMEN
Affiliation:Author Mutlu is an associate professor in the Dept. of Food Engineering &Bioengineering Division, Hacettepe Univ., 06532 Ankara, Türkiye. Authors HizarcioĞlu and Gökmen are Research Assistants in the Dept. of Food Engineering, Hacettepe Univ., 06532 Ankara, Türkiye.
Abstract:The kinetics of adsorption of patulin on activated carbon were studied at different initial patulin concentrations (100–400 ppb) for the temperature range 20–80°C. Apparent adsorption rate constants (kaapp) were changed from 1.07 × 10?3 to 1.86 × 10?3 g?1 min?1 while the temperature increased from 20 to 80°C. For equilibrium adsorption curves; the Langmuir model was attempted and model parameters (K and Q°) were obtained for different temperatures. Energy of activation and heat of adsorption were determined in a batch adsorption system (Ea= 2.02 kcal/mol and ΔH = 2.24 kcal/mol). The adsorption occurred endothermically and by physical mechanisms.
Keywords:patulin  juice  adsorption kinetics  activation energy  heat of adsorption
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