Photoalignment dynamics of azo dyes series with different coordination metals |
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Authors: | Vadim S Mikulich Alexander A Muravsky Anatoli A Murauski Iryna N Kukhta Vladimir E Agabekov Rashid Altamimi |
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Affiliation: | 1. Institute of Chemistry of New Materials, NAS of Belarus, , Minsk, Belarus;2. Petrochemicals Research Institute, KACST, , Riyadh, Saudi Arabia |
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Abstract: | There are many photoaligned azo dyes that can be used for orientation of liquid crystals in various display devices. However, the structure of these compounds needs to be optimized to increase the rate of the process of molecule photoalignment, as well as to spread the application of these compounds. The main coordination metal that presents in the molecules of azo dyes is sodium derivatives. The use of other alkali metals remains an open question. We used quantum‐chemical computation methods and reversible intermolecular bonding model to determine the effect of metal coordination on the velocity of photoalignment. The theoretical predictions were experimentally verified using sodium, potassium, lithium, and cesium salts of the model azo dye synthesized by us. We conclude that potassium azo derivatives are the fastest, ceteris paribus. |
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Keywords: | photoalignment intermolecular bonds azo dye orientation dynamics liquid crystals |
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