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Mechanical reliability of Ce0.8Gd0.2O2?δ-FeCo2O4 dual phase membranes synthesized by one-step solid-state reaction |
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| Authors: | Fanlin Zeng Jürgen Malzbender Stefan Baumann Wenyu Zhou Mirko Ziegner Arian Nijmeijer Olivier Guillon Ruth Schwaiger Wilhelm Albert Meulenberg |
| Affiliation: | 1. Institute of Energy and Climate Research (IEK), Forschungszentrum Jülich GmbH, Jülich, Germany;2. Institute of Energy and Climate Research (IEK), Forschungszentrum Jülich GmbH, Jülich, Germany
Faculty of Science and Technology, Inorganic Membranes, University of Twente, Enschede, The Netherlands;3. Faculty of Science and Technology, Inorganic Membranes, University of Twente, Enschede, The Netherlands;4. Institute of Energy and Climate Research (IEK), Forschungszentrum Jülich GmbH, Jülich, Germany Chair of Energy Engineering Materials, RWTH Aachen University, Aachen, Germany |
| Abstract: | Ce0.8Gd0.2O2?δ-FeCo2O4 composites are attractive candidate materials for high-purity oxygen generation providing robust chemical stability. Aiming for future industrial applications, a feasible solid-state reaction process with one thermal processing step was used to synthesize 50 wt% Ce0.8Gd0.2O2?δ:50 wt% FeCo2O4 and 85 wt% Ce0.8Gd0.2O2?δ:15 wt% FeCo2O4 composites. Mechanical reliabilities of the sintered membranes were assessed based on the characterized mechanical properties and subcritical crack growth behavior. In general, the fracture strengths of as-sintered membranes were reduced by tensile residual stresses and microcracks. In particular, the enhanced subcritical crack growth behavior, which leads to limited stress tolerance and high failure probability after a 10-year operation, was evaluated in more detail. Further materials and processing improvements are needed to eliminate the tensile stress and microcracks to warrant a long-term reliable operation of the composites. |
| Keywords: | dual phase ceramic composite lifetime prediction mechanical properties oxygen transport membrane residual stress |