| Affiliation: | 1. School of Applied Physics and Materials, Wuyi University, Jiangmen, P.R. China State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, PR China;2. School of Applied Physics and Materials, Wuyi University, Jiangmen, P.R. China;3. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, PR China |
| Abstract: | With great economic benefits, white LEDs (w-LEDs) have aroused worldwide attention. For phosphor-converted w-LED, highly efficient emission and good thermal stability of phosphor are significant parameters in practical application. Here, a yellow-orange garnet-structural phosphor, Ba2YAl3Si2O12:xCe3+ (x = 0-0.1) (BYAS:xCe3+) was developed by solid solution design. The broad emission spectrum of the as-synthesized phosphor could guarantee the effective increase of the color rendering index when it is combined with the InGaN blue chip. Benefiting from the garnet-type highly rigid framework, BYAS:xCe3+ exhibits an excellent thermal stability (50%@673K of the initial integrated intensity at 280 K) as well as high absolute quantum efficiency (80.4%@460 nm excitation light). Utilizing the approach of “phosphor-in-glass” (PiG), a high-power warm w-LED is achieved based on a blue LED plus PiG and the illuminance of this w-LED device can be as high as 4227 lx. |
