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Semivolatile organic compounds in French schools: Partitioning between the gas phase,airborne particles and settled dust
Authors:Wenjuan Wei  Claire Dassonville  Sutharsini Sivanantham  Anthony Gregoire  Fabien Mercier  Barbara Le Bot  Laeticia Malingre  Olivier Ramalho  Mickaël Derbez  Corinne Mandin
Affiliation:1. Scientific and Technical Center for Building (CSTB), Health and Comfort Department, French Indoor Air Quality Observatory (OQAI), University of Paris-Est, Marne la Vallée, France;2. Scientific and Technical Center for Building (CSTB), Health and Comfort Department, French Indoor Air Quality Observatory (OQAI), University of Paris-Est, Marne la Vallée, France

Contribution: Data curation, Writing - review & editing;3. Scientific and Technical Center for Building (CSTB), Health and Comfort Department, French Indoor Air Quality Observatory (OQAI), University of Paris-Est, Marne la Vallée, France

Contribution: Data curation, ?Investigation, Writing - review & editing;4. EHESP, Inserm, Irset (Institut de recherche en santé, environnement et travail) - UMR_S1085, Univ Rennes, Rennes, France

Contribution: Methodology, Writing - review & editing;5. EHESP, Inserm, Irset (Institut de recherche en santé, environnement et travail) - UMR_S1085, Univ Rennes, Rennes, France;6. Scientific and Technical Center for Building (CSTB), Health and Comfort Department, French Indoor Air Quality Observatory (OQAI), University of Paris-Est, Marne la Vallée, France

Contribution: Methodology, Project administration, Supervision, Writing - review & editing

Abstract:The indoor environmental quality in classrooms can largely affect children's daily exposure to indoor chemicals in schools. To date, there has not been a comprehensive study of the concentrations of semivolatile organic compounds (SVOCs) in French schools. Therefore, the French Observatory for Indoor Air Quality (OQAI) performed a field study of SVOCs in 308 nurseries and elementary schools between June 2013 and June 2017. The concentrations of 52 SVOCs, including phthalates, polybrominated diphenyl ethers (PBDEs), polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), synthetic musks, and pesticides, were measured in air and settled dust (40 SVOCs in both air and dust, 12 in either air or dust). The results showed that phthalates had the highest concentrations among the SVOCs in both the air and dust. Other SVOCs, including tributyl phosphate, fluorene, phenanthrene, gamma-hexachlorocyclohexane (gamma-HCH, lindane), galaxolide, and tonalide, also showed high concentrations in both the air and dust. Theoretical equations were developed to estimate the SVOC partitioning between the air and settled dust from either the octanol/air partition coefficient or the boiling point of the SVOCs. The regression constants of the equations were determined using the data set of the present study for phthalates and PAHs.
Keywords:children  classroom  flame retardant  phthalate  PM2  5  SVOC
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