Topological hardening through oxygen triclusters in calcium aluminosilicate glasses |
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Authors: | Rebecca S. Welch Kuo-Hao Lee Collin J. Wilkinson Madoka Ono Caio B. Bragatto John C. Mauro |
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Affiliation: | 1. Department of Materials Science and Engineering, The Pennsylvania State University, University Park, PA, USA;2. Materials Integration Laboratories, AGC Inc, Yokohama, Japan;3. Department of Physics, Coe College, Cedar Rapids, IA, USA |
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Abstract: | Molecular dynamics simulations and topological constraint theory are used to study the impact of oxygen triclusters in the calcium aluminosilicate glass system at ratios of 0.6, 1, 1.5, 2, and 4 [Al2O3]/[CaO]. Negligible percentages (less than ~3%) of five-coordinated Al structures are found at all ratios. Up to ~27% three-coordinated oxygens, also known as triclusters, are found at the highest ratio of [Al2O3]/[CaO]. A topological constraint model, which considers additional constraints provided by triclusters, is created to predict the glass transition temperature, hardness, and Young's modulus. The models are used to elucidate the role of triclusters in glass properties. Analysis of topological constraints shows that triclusters can potentially increase the glass hardness within the calcium aluminosilicate system. The results are also compared to oxynitride glasses. Triclusters show the same ability as nitrogen to increase the glass hardness but are less effective at increasing the Young's modulus. |
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Keywords: | calcium aluminosilicate glass molecular dynamics oxygen triclusters topological constraint theory |
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