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双循环法测定等液相组成汽—液平衡数据的研究及其应用
引用本文:陈庚华,章连众.双循环法测定等液相组成汽—液平衡数据的研究及其应用[J].高校化学工程学报,1990,4(4):302-312.
作者姓名:陈庚华  章连众
作者单位:浙江大学化学系 (陈庚华,章连众),浙江大学化学系(韩世钧)
摘    要:本工作研究了用双循环法测定等液相组成汽-液平衡数据的特点,建立了一种新型的SG—Ⅱ双循环沸点仪,测定了乙醇-正已烷体系15个浓度时的等液相组成数据,并推算了该体系298.15K至328.15K时的等温汽-液平衡、过量自由焓和微分汽化热。

关 键 词:双循环法  等液相  汽液平衡

Determination of VLE Data under Constant Liquid Composition by Double Circulation Method: Investigation and Applictions
Chen Genghua Zhang Lianzhong Han shijun.Determination of VLE Data under Constant Liquid Composition by Double Circulation Method: Investigation and Applictions[J].Journal of Chemical Engineering of Chinese Universities,1990,4(4):302-312.
Authors:Chen Genghua Zhang Lianzhong Han shijun
Abstract:Experimental determination of VLE data under constant liquid composition (isoplethic VLE data )by double circulation method was studied. By use of a new type double circulation ebulliometer, Isoplethic VLE data were determined under 15 different concentrations for the system ethanol-n-hexane in a temperature range from 298K to 331K. Isothermal VLE. excess free enthalpy, and differential heat of vaporization are calculated from 298. 15K to 328. 15K.
Keywords:Isoplethic VLE  Ethanol-n-hexane  Boiling point apparatus  Differential heat of vaporization  Excess free enthalpy  
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