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聚苯胺/蒙脱土纳米复合微波吸收材料的制备及表征
引用本文:王鹏,王庆昭,邱光磊,范俊峰,邓景波. 聚苯胺/蒙脱土纳米复合微波吸收材料的制备及表征[J]. 工程塑料应用, 2006, 34(1): 44-47
作者姓名:王鹏  王庆昭  邱光磊  范俊峰  邓景波
作者单位:山东科技大学化学与环境工程学院,青岛,266510;72679部队,肥城,271600
摘    要:以十二烷基苯磺酸(DBSA)作为乳化剂和掺杂剂,通过乳液聚合的方法制备了DBSA掺杂聚苯胺/蒙脱土(PANI/MMT)纳米复合材料,采用X射线衍射仪、傅立叶变换红外光谱仪、四探针电导率仪和矢量网络分析仪进行了初步表征。经测量和计算发现,PANI/MMT纳米复合材料与石蜡质量比为1∶1的2mm厚试样在2~18GHz范围内具有微波吸收性能,在13~14GHz范围内反射损耗小于-10dB,在13GHz处的最大反射损耗为-10.3dB。

关 键 词:聚苯胺  蒙脱土  纳米复合材料  电磁参数  微波吸收
收稿时间:2005-10-16
修稿时间:2005-10-16

PREPARATION AND CHARACTERIZATION OF POLYANILINE/MONTMORILLONITE NANOCOMPOSITES FOR MICROWAVE-ABSORBING
Wang Peng,Wang Qingzhao,Qiu Guanglei,Fan Junfeng,Deng Jingbo. PREPARATION AND CHARACTERIZATION OF POLYANILINE/MONTMORILLONITE NANOCOMPOSITES FOR MICROWAVE-ABSORBING[J]. Engineering Plastics Application, 2006, 34(1): 44-47
Authors:Wang Peng  Wang Qingzhao  Qiu Guanglei  Fan Junfeng  Deng Jingbo
Affiliation:1.Faculty of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266510, China;2.Unit 72679 of PLA, Feicheng 271600, China
Abstract:Polyaniline (PANI) /montmorillonite (MMT) nanocomposite was synthesized by emulsion polymerization using dodecylbenzensulfonic acid (DBSA) as dopant and emulsifier. The properties of the nanocomposite were characterized by X-ray diffratometer, FT-IR, conductivity measuring apparatus and vector analyzer. Measurement and calculation results showed that a 2 mm thick sample containing 50% PANI/MMT nanocomposite was capable of absorbing 2-18 GHz microwaves whose reflection loss was less than -10 dB within the frequency range of 13-14 GHz, while the maximum reflection loss was -10.3 dB at 13 GHz.
Keywords:polyaniline   montmorillonite   nanocomposite   electromagnetic paramelter   microwave-absorbing
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