| MAP-POSS改性丙烯酸酯/苯乙烯乳胶的合成与表征 |
| |
| 引用本文： | 张媛媛,张雪芳,张彩云,高俊刚.MAP-POSS改性丙烯酸酯/苯乙烯乳胶的合成与表征[J].涂料工业,2010,40(3). |
| |
| 作者姓名： | 张媛媛 张雪芳 张彩云 高俊刚 |
| |
| 作者单位： | 河北大学化学与环境科学学院,河北保定,071002 |
| |
| 摘 要： | 为改进丙烯酸乳胶涂料的性能,以丙烯酸和丙烯酸丁酯的低聚物为乳化剂,甲基丙烯酰氧丙基笼型倍半硅氧烷(MAP-POSS)为改性剂,制备了丙烯酸酯/苯乙烯共聚乳胶涂料;研究了乳液聚合反应的动力学,用红外光谱(FT-IR),热重分析(TG)等方法进行了结构表征及其性能测试。结果表明MAP-POSS与其他单体发生了共聚反应,该乳液稳定性好,耐水性、耐热性,耐化学性等综合性能得到一定的提高。
|
| 关 键 词： | 乳液聚合 笼型倍半硅氧烷 聚合动力学 热分析 |
Synthesis and Characterization of MAP-POSS Modified Acrylate-Styrene Latex |
| |
| Zhang Yuanyuan,Zhang Xuefang,Zhang Caiyun,Gao Jungang.Synthesis and Characterization of MAP-POSS Modified Acrylate-Styrene Latex[J].Paint & Coatings Industry,2010,40(3). |
| |
| Authors: | Zhang Yuanyuan Zhang Xuefang Zhang Caiyun Gao Jungang |
| |
| Affiliation: | Zhang Yuanyuan,Zhang Xuefang,Zhang Caiyun,Gao Jungang (College of Chemistry , Environmental Science,Hebei University,Baoding,Hebei 071002,China) |
| |
| Abstract: | The title copolymeric latex coatings of acrylate and styrene(St) were prepared by copolymerization in the presence of the poly(butylacrylate/acrylic acid) oligomer as emulsifier,K2S2O8(KPS) as initiator and MAP-POSS as modifier.The reaction kinetics was investigated and the structure and properties of copolymer and latex were characterized by FT-IR,thermogravimetric analysis(TGA) and other methods.The results showed that the emulsion had good stability,water resistance,heat resistance and chemical resistanc... |
| |
| Keywords: | emulsion polymerization cage silsesquioxanes polymerization kinetics thermal analysis |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
