Isotope Exchange Capacity on Li4SiO4 and Comparison of Tritium Inventory in Various Solid Breeder Blankets

It has been pointed out by the present authors that it is essential to understand such mass transfer steps as diffusion of tritium in the grain of a breeder material, absorption of water vapor into bulk of the grain, adsorption of water on surface of the grain, and exchange capacity of tritium to be trapped to surface of the grain together with two types of isotope exchange reactions for evaluation of the tritium inventory in a solid breeder blanket under various conditions. The isotope exchange capacity on the Li₄SiO₄ surface is experimentally obtained in this study. Most of the properties required for evaluation of the tritium inventory for various blanket materials have been already quantified by the present authors. Then it has become possible to compare the tritium inventory in solid breeder blankets packed with either Li₂O, LiAlO₂, Li₂ZrO₃, Li₂TiO₃ or Li₄SiO₄ using the calculation model previously presented by the present authors.