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一个大学生课外科技创新活动简介
引用本文:邓强,徐敬芳,汤颖. 一个大学生课外科技创新活动简介[J]. 广州化工, 2011, 39(13): 189-191
作者姓名:邓强  徐敬芳  汤颖
作者单位:西安石油大学化学化工学院,陕西,西安,710065
摘    要:在化学学科大学生科技创新活动中制作了简易的实验装置,研究了在盐酸催化的亚硝酸钠(NaNO2)与氯化铵(NH4Cl)反应动力学,结果显示:NaNO2与NH4Cl水溶液的反应为二级反应;反应的速率常数与体系中H+的浓度成正比;活化能为50.26 kJ/mol;NaNO2与NH4Cl反应的动力学方程为dC/dt=-2.066×107CH+e-6045/TC2。该实验能有效地培养学生对于化学动力学部分内容的理解和综合应用能力。

关 键 词:化学生热  动力学  活化能

An Extracurricular Scientific and Technology Active for Chemistry College Students
DENG Qiang,XU Jing-fang,TANG Ying. An Extracurricular Scientific and Technology Active for Chemistry College Students[J]. GuangZhou Chemical Industry and Technology, 2011, 39(13): 189-191
Authors:DENG Qiang  XU Jing-fang  TANG Ying
Affiliation:(College of Chemistry and Engineering,Xi’an Shiyou University,Shaanxi Xi’an 710065,China)
Abstract:A simple experimental devices were established for the study of the kinetics of reaction between NaNO2 and NH4Cl in the practice of extracurricular scientific and technology active of college students.The results showed that the reaction was a second order reaction and the reaction rate constant(k) was in direction proportion to the H+ concentration in the system.The activation energy of this reaction was 50.26 kJ/mol.The kinetic formulation of this reaction was dC/dt=-2.066×107CH+e-6045/TC2.Based on this experiment,the comprehesunsion for chemical kinetic and its application of students would developed.
Keywords:chemical heat-generation  kinetics  activation energy
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