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Changes in Structure, Rheology, and Water Mobility of Apple Tissue Induced by Osmotic Dehydration with Glucose or Trehalose
Authors:Sebastián Vicente  Andrea B Nieto  Karina Hodara  María A Castro  Stella M Alzamora
Affiliation:1. Departamento de Industrias, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, 1428, Buenos Aires, Argentina
2. Consejo Nacional de Investigaciones Cient??ficas y T??cnicas, Buenos Aires, Argentina
3. Departamento de M??todos Cuantitativos y Sistemas de Informaci??n, Facultad de Agronom??a, Universidad de Buenos Aires, Av. San Mart??n 4453, C1417DSE, Buenos Aires, Argentina
4. Departamento de Biodiversidad y Biolog??a Experimental, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, 1428, Buenos Aires, Argentina
Abstract:The impact of osmotic dehydration to water activity (a w) at 0.97 or 0.94 with glucose or trehalose solutions on structure (optical and transmission electronic microscopy observations), rheological properties (small-scale dynamic oscillatory and creep/recovery measurements and large-scale compression force-deformation testing) and water mobility (1H-NMR spectra) of parenchymatous apple tissue was investigated. In general, the nature and the concentration of sugar employed significantly affected the material properties and the structure of apple tissue. A dramatic loss in rigidity (E d); an increase in deformation at rupture (?? R R ), creep compliances (J 0, J 1, and J 2), and fluidity (1/?? 0) and a decrease in storage (G??) and loss (G??) moduli, true rupture stress (?? R R ), and proton transverse relaxation times (T 2i) were induced by osmotic treatments. ?? R R , C 1, and T 2i parameters allowed to discriminate between the sugars used as osmotic agents while the different a w levels for each sugar resulted in changes in ?? R R , W, and T 2i values. Loss of turgor due to plasmolysis or rupture of membranes and desorganization/degradation of walls allowed explaining, at least partially, the changes in material parameters.
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