| 碳酸二甲酯本体氯化反应合成固体光气 |
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| 引用本文： | 姚日生,柴多里,韩效钊. 碳酸二甲酯本体氯化反应合成固体光气[J]. 精细化工中间体, 1999, 0(5) |
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| 作者姓名： | 姚日生 柴多里 韩效钊 |
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| 作者单位： | 合肥工业大学!230009 |
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| 摘 要： | 研究了ＢＰＯ 引发以及光／ＢＰＯ 复合引发在碳酸二甲酯（ＤＭＣ） 本体氯化反应中的作用。结果表明随着ＢＰＯ 添加量及光功率的增加， 氯化反应速率加快， 且ＢＰＯ 的添加量以不超过４ｇ／ｍｏｌＤＭＣ为宜， 过量的ＢＰＯ 在反应中会促使生成的固体光气分解。
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| 关 键 词： | 过氧化苯甲酰 紫外光 碳酸二甲酯 本体 氯化 固体光气 |
The Synthesis of Triphosgene by Chlorination of Dimethyl Carbonate |
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| YAO Risheng CAI Duoli HAN Xiaozhao. The Synthesis of Triphosgene by Chlorination of Dimethyl Carbonate[J]. Fine Chemical Intermediates, 1999, 0(5) |
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| Authors: | YAO Risheng CAI Duoli HAN Xiaozhao |
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| Affiliation: | Hefei University of Technology Changsha 230009 |
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| Abstract: | An investigation was made of the effects of BPO and UV/BPO irradiation on the chlorination of dimethyl carbonate bulk . It was shown that the chlorination rate increased with BPO addition and light powder raising. From 2 to 4 g/mol DMC was suitable for BPO addition, whose overbalance would make the triphosgene decompose. |
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| Keywords: | BPO UV dimethyl carbonate bulk chlorination triphosgene |
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