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催化湿式二氧化氯氧化法的研究
引用本文:汪萍,董俊明. 催化湿式二氧化氯氧化法的研究[J]. 工业水处理, 2006, 26(9): 21-24
作者姓名:汪萍  董俊明
作者单位:湖南师范大学化学化工学院,湖南,长沙,410081;湖南城建职业技术学院,湖南,湘潭,411103
摘    要:通过浸渍法制备了包含四类主活性组分的负载型催化剂,用于二氧化氯催化湿式氧化(CWCDO)处理印染废水、有机农药废水.由实验确定了催化湿式氧化的条件,结果表明,四元组合MnO2-CuO-CeO2-V2O5(质量比为2:4:1:1)催化剂性能较好,反应在常温常压下,维持pH为3.0~5.0,反应时间为30 min时,COD的去除率大于85%,色度去除率大于90%.

关 键 词:催化湿式二氧化氯氧化  负载型催化剂  浸渍法  染料与农药废水
文章编号:1005-829X(2006)09-0021-04
收稿时间:2006-03-05
修稿时间:2006-03-05

Study on catalytic wet chlorine dioxide oxidation method
Wang Ping,Dong Junming. Study on catalytic wet chlorine dioxide oxidation method[J]. Industrial Water Treatment, 2006, 26(9): 21-24
Authors:Wang Ping  Dong Junming
Affiliation:1. College of Chemistry and Chemical Engineering,Hunan Normal University, Changsha 410081, China; 2. Hunan Urban Construction College , Xiangtan 411103, China
Abstract:Four main active components loaded catalysts have been prepared by means of impregnant.And the loaded catalysts could be used in the course of the catalytic wet chlorine dioxide oxidation(CWCDO) to treat the printing-dyeing and organic-pesticide wastewater.The conditions of CWCDO are gained through experiments.And the results show that the better catalysts with high catalytic ability have been prepared with the four-components catalysts of MnO2-CuO-CeO2-V2O5(mass ratio =2:4:1:1).Finally,under the reaction condition of ordinary temperature and pressure,maintaining pH 3-5,and reaction time 30 min,the chemical oxygen demand(COD) removals rate and decolorization rate are over 85% and 90%,respectively.
Keywords:catalytic wet chlorine dioxide oxidation(CWCDO)  loaded catalysts  impregnated method  printing-dyeing and organic-pesticide wastewater
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