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Ambient- to elevated-temperature fracture and fatigue properties of Mo-Si-B alloys: Role of microstructure
Authors:J J Kruzic  J H Schneibel  R O Ritchie
Affiliation:(1) the Department of Mechanical Engineering, Oregon State University, 97331 Corvallis, OR;(2) Oak Ridge National Laboratory, Metals and Ceramics Division, 37831 Oak Ridge, TN;(3) the Materials Sciences Division, Lawrence Berkeley National Laboratory, and the Department of Materials Science and Engineering, University of California, 94720 Berkeley, CA
Abstract:Ambient- to elevated-temperature fracture and fatigue-crack growth results are presented for five Mo-Mo3Si-Mo5SiB2-containing α-Mo matrix (17 to 49 vol pct) alloys, which are compared to results for intermetallic-matrix alloys with similar compositions. By increasing the α-Mo volume fraction, ductility, or microstructural coarseness, or by using a continuous α-Mo matrix, it was found that improved fracture and fatigue properties are achieved by promoting the active toughening mechanisms, specifically crack trapping and crack bridging by the α-Mo phase. Crack-initiation fracture toughness values increased from 5 to 12 MPa√m with increasing α-Mo content from 17 to 49 vol pct, and fracture toughness values rose with crack extension, ranging from 8.5 to 21 MPa√m at ambient temperatures. Fatigue thresholds benefited similarly from more α-Mo phase, and the fracture and fatigue resistance was improved for all alloys tested at 1300 °C, the latter effects being attributed to improved ductility of the α-Mo phase at elevated temperatures.
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