| 几种常用燃速催化剂对P(BAMO/AMMO)含能粘合剂热分解性能的影响 |
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| 引用本文： | 王刚,葛震,罗运军.几种常用燃速催化剂对P(BAMO/AMMO)含能粘合剂热分解性能的影响[J].含能材料,2014,22(5):641-645. |
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| 作者姓名： | 王刚 葛震 罗运军 |
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| 作者单位： | 北京理工大学材料学院,北京,100081 |
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| 摘 要： | 用热重(TG)和差示扫描量热法(DSC)研究了Cu O、Fe2O3、碳黑(CB)、Pb CO3、Bi2O3、(NH4)2Cr2O7对P(BAMO/AMMO)含能粘合剂热分解性能的影响。结果表明:6种催化剂使P(BAMO/AMMO)粘合剂的起始分解温度向低温方向移动,叠氮基团放热分解反应提前,促进了粘合剂放热分解反应,升温速率10℃·min-1时,CB和Pb CO3使粘合剂的起始分解温度分别向低温方向移动8.3℃和24.2℃。Cu O、Fe2O3、Pb CO3、(NH4)2Cr2O7使P(BAMO/AMMO)粘合剂中叠氮基团的表观分解热分别增加0.05,0.09,0.10,0.06 k J·g-1,而CB和Bi2O3使叠氮基团的表观分解热减小。
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| 关 键 词： | 分析化学 含能粘合剂 P(BAMO/AMMO) 燃速催化剂 热分解 |
| 收稿时间： | 2013/11/14 0:00:00 |
| 修稿时间： | 2014/1/17 0:00:00 |
Effect of Several Burning Rate Catalysts on the Thermal Decomposition Properties of P(BAMO/AMMO) Energetic Binder |
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| WANG Gang,GE Zhen and LUO Yun-jun.Effect of Several Burning Rate Catalysts on the Thermal Decomposition Properties of P(BAMO/AMMO) Energetic Binder[J].Chinese Journal of Energetic Materials,2014,22(5):641-645. |
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| Authors: | WANG Gang GE Zhen and LUO Yun-jun |
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| Affiliation: | School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China;School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China;School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China |
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| Abstract: | |
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| Keywords: | material science energetic binder P(BAMO/AMMO) burning rate catalyst thermal decomposition |
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