氧化铈膜制备及其耐腐蚀性能

采用不同的制备溶液及制备参数在X80钢表面制备出不同的氧化铈膜,并对其耐腐蚀性能进行了研究.利用扫描电镜、能谱仪、XRD、拉曼光谱、接触角测试仪对不同的氧化铈膜腐蚀前后的表面形貌、元素、物相及亲水性进行了分析,利用电化学工作站对不同的氧化铈膜在3.5wt.％NaCl溶液中的开路电位、线性极化电阻、交流阻抗、极化曲线进行...

Preparation and anti-corrosion performance of cerium oxide film

Cerium oxide films on surface of X80 steel were prepared with different solutions and parameters, and their corrosion properties were investigated. The surface morphology, element, phase, and hydrophilicity of the film before and after corrosion were analyzed by using scanning electron microscopy (SEM), energy disperse spectroscopy (EDS), X-ray diffraction (XRD), Raman spectrum, and contact angle meter. The open circuit potential (OCP), linear polarization resistance (LPR), electrochemical impedance spectroscopy (EIS), and polarization curve (PC) of the film in 3.5wt.% NaCl solution were obtained based on electrochemical workstation. Results show that H₂O in solution caused cracking in the film, whereas the enhancement of current density did not cause such cracks. The surface energy of the film could be increased by enhancing current density or increasing preparation time. H₂O in solution could improve the corrosion resistance of the film, and the corrosion resistance was also obviously improved by increasing current density, while preparation time had little effect on the anti-corrosion performance of the film. Optimizing preparation parameters of cerium oxide film can significantly improve its corrosion resistance.