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12Cr1MoV钢连续冷却过程中P的晶界偏聚
引用本文:杨尚林,李莉,田无边,杨亚卓,李庆芬.12Cr1MoV钢连续冷却过程中P的晶界偏聚[J].材料热处理学报,2003,24(4):33-36.
作者姓名:杨尚林  李莉  田无边  杨亚卓  李庆芬
作者单位:哈尔滨工程大学,机电工程学院,黑龙江,哈尔滨,150001
基金项目:国家自然科学基金资助(59971042);国防科工委基础研究资助(J1600E001).
摘    要:采用分步冷却工艺,研究了连续冷却过程中12Cr1MoV钢中P的非平衡晶界偏聚过程,实际测得在813K恒温45h时,P在晶界的偏聚量为4.1at%,相应的理论计算等效时问te(813K)=42.558h时,P在晶界的偏聚量为4.4at%,表明实验结果与理论计算值相吻合。从而说明晶界偏聚的等效时间理论能很好地解释分步冷却工艺中P的非平衡晶界偏聚动力学和分步冷却工艺加速脆化的机理。

关 键 词:分步冷却  连续冷却  晶界偏聚  等效时间  临界时间
文章编号:1009-6264(2003)04-0033-04

Segregation of P at Grain-boundary of 12CrlMoV Steel in Continuous Cooling Process
YANG Shang-lin,LI Li,TIAN Wu-bian,YANG Ya-zhuo,LI Qing-fen.Segregation of P at Grain-boundary of 12CrlMoV Steel in Continuous Cooling Process[J].Transactions of Materials and Heat Treatment,2003,24(4):33-36.
Authors:YANG Shang-lin  LI Li  TIAN Wu-bian  YANG Ya-zhuo  LI Qing-fen
Abstract:By step cooling process, the non-equilibrium segregation process of P at grain-boundary of 12Cr1MoV steel in continuous cooling process is investigated. The measured value of segregation of P at grain-boundary is 4\^1 at % for the steel at 813K isothermal holding 45h, and the corresponding calculated result is 4\^4 at % while the effective time is 42\^558h. The results show that the experimental data accords with the calculated result. This indicates the theoretic segregation model at grain-boundary can be used to explain the dynamical segregation process of P at grain-boundary in step cooling process and the mechanism of accelerating embrittlement of step cooling.
Keywords:step cooling  continuum cooling  grain-boundary segregation  effective time  critical time
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