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Development of the efficient TiO2 photocatalyst in photoassisted selective catalytic reduction of NO with NH3
Authors:Seiji Yamazoe   Taro Okumura   Kentaro Teramura  Tsunehiro Tanaka  
Affiliation:

aDepartment of Molecular Engineering, Graduate School of Engineering, Kyoto University, Kyoto 615-8510, Japan

bDepartment of Chemical System Engineering, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan

Abstract:Photoassisted selective catalytic reduction (photo-SCR) of NO with NH3 in the presence of O2 takes place at room temperature over TiO2 photocatalyst. From the results of photo-SCR reaction over various TiO2, we found that JRC-TIO-11 exhibited the best activity. The reaction activity correlated to the amount of acid sites of TiO2, but did not depend on the specific surface area and crystal diameter. The mixture of rutile and anatase shows higher activity than any of the corresponding TiO2 single phase catalyst.
Keywords:TiO2   Photocatalyst   SCR   NH3   NO
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