Kinetic study on copolymerization of ethylene and 1‐hexene catalyzed by Cp2ZrCl2/MAO catalytic system |
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| Authors: | Jianfeng Wang Li Wang Haoqi Gao Wenqin Wang Guohua Jiang Xiaocheng Dong Wei Wang Lianfang Feng |
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| Affiliation: | 1. State Key Laboratory of Polymer Reaction Engineering, College of Materials Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, People's Republic of China;2. Ningbo University of Technology, Ningbo 315011, People's Republic of China |
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| Abstract: | The kinetics of ethylene and 1‐hexene copolymerization catalyzed by Cp2ZrCl2/MAO was studied. A new kinetic mathematical model that takes the reactivation effect of MAO into account has been developed. Applying this model, the good agreement between the experimental data and the fitting profiles was achieved. POLYM. ENG. SCI., 47:540–544, 2007. © 2007 Society of Plastics Engineers |
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