| 模板法制备二氧化硅纳米管及其表征 |
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| 引用本文： | 郑斌,李元庆,朱路平,杨洋,付绍云. 模板法制备二氧化硅纳米管及其表征[J]. 化工学报, 2007, 58(10): 2641-2646 |
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| 作者姓名： | 郑斌 李元庆 朱路平 杨洋 付绍云 |
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| 作者单位： | 中国科学院理化技术研究所 |
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| 摘 要： | 以正硅酸乙酯（TEOS）为原料，D〖DK〗，L 酒石酸铵为模板制备了高产率、尺寸均匀、大长径比的二氧化硅纳米管。借助透射电子显微（TEM）、扫描电子显微（SEM）、电子能谱（EDX）和X射线衍射（XRD）等分析方法对样品进行表征，探讨了二氧化硅纳米管的形成机理，并考察了实验条件对二氧化硅纳米管的产率和形貌等的影响。研究结果表明，静置时间、TEOS的滴加速率以及氨水用量对纳米管的形成有明显影响，而温度对纳米管形成的影响不明显。
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| 关 键 词： | 二氧化硅纳米管 正硅酸乙酯 酒石酸铵 模板 模板法制备 二氧化硅纳米管 表征 ammonium TEOS synthesized nanotubes Silica characterization 管形 温度 用量 氨水 加速率 静置时间 结果 研究 影响 产率 实验条件 |
| 文章编号： | 0438-1157（2007）10-2641-06 |
| 收稿时间： | 2006-11-01 |
| 修稿时间： | 2006-11-01 |
Silica nanotubes synthesized from TEOS with ammonium D,L-tartrate as template and their characterization |
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| ZHENG Bin,LI Yuanqing,ZHU Luping,YANG Yang,FU Shaoyun. Silica nanotubes synthesized from TEOS with ammonium D,L-tartrate as template and their characterization[J]. Journal of Chemical Industry and Engineering(China), 2007, 58(10): 2641-2646 |
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| Authors: | ZHENG Bin LI Yuanqing ZHU Luping YANG Yang FU Shaoyun |
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| Affiliation: | 1Tecknical Institute of Physics and Chemistr y , Chinese Academy of Sciences, Beij in g 100080, 2Graduate Sckool of Chinese Academy of Sciences, Beijing 100039, China |
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| Abstract: | Silica nanotubes with high yield,uniform size and large aspect ratio were synthesized from hydrodyzing tetraethyl orthosilicate(TEOS)using ammonium D,L-tartrate as template.The prepared products were characterized with transmission electron microscopy(TEM),scanning electron microscopy(SEM),energy dispersive X-ray analysis(EDX)and powder X-ray diffraction(XRD).The formation mechanism of the silica nanotubes and the influence of synthesis conditions on the formation of the silica nanotubes were investigated.The results revealed that the morphology and yield of the silica nanotubes were sensitive to TEOS addition speed,aging time after TEOS addition and ammonia concentration,but not sensitive to reaction temperature. |
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| Keywords: | silica nanotubes tetraethyl orthosilicate ammonium D L-tartrate template |
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