| 配合物Ni（bacbh）2（Py）2的合成、晶体结构及热稳定性 |
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| 引用本文： | 刘娟,王亮,王栋,张斌.配合物Ni（bacbh）2（Py）2的合成、晶体结构及热稳定性[J].应用化工,2012,41(2):248-251. |
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| 作者姓名： | 刘娟 王亮 王栋 张斌 |
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| 作者单位： | 1. 西安工程大学环境与化学工程学院,陕西西安,710048
2. 上海外高桥造船有限公司品保部,上海,200137 |
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| 基金项目： | 陕西省自然科学基金项目(2009JM2012) |
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| 摘 要： | 以苯亚甲基苯乙酮-4-氯苯甲酰腙为配体,水热合成了一个镍的单核配合物Ni(bacbh)2(Py)2(bacbh:苯亚甲基苯乙酮-4-氯苯甲酰腙;Py:吡啶),并利用元素分析、红外光谱、X射线单晶衍射及热失重分析对配合物进行了表征。该配合物为单斜晶系,空间群为P2(1)/n,晶胞学数据:a=1.344 3(6)nm,b=2.471 7(12)nm,c=1.465 1(7)nm,β=98.47°,V=4.815(4)nm3,Z=4,μ=0.561 mm-1,Dc=1.292 mg/m3,F(000)=1 944,最终偏离因子I>2sigma(I)]R1=0.038 6,wR2=0.096 1(all data),GOF=1.007(CCDC:840865)。
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| 关 键 词： | 酰腙 水热合成 配合物 晶体结构 热稳定性 |
Synthesis, crystal structure and thermal stability of Ni (bacbh) 2 (Py) 2 complex |
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| LIU Juan
,
WANG Liang
,
WANG Dong
,
ZHANG Bin.Synthesis, crystal structure and thermal stability of Ni (bacbh) 2 (Py) 2 complex[J].Applied chemical industry,2012,41(2):248-251. |
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| Authors: | LIU Juan WANG Liang WANG Dong ZHANG Bin |
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| Affiliation: | 1.School of Environmental & Chemical Engineering,Xi’an Polytechnic University,Xi’an 710048,China;2.Quality Assurance Department,Shanghai Waigaoqiao Shipbuilding Co.,Ltd.,Shanghai 200137,China) |
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| Abstract: | Amononuclear complex Ni(bacbh)2(Py)2(bacbh=benzylidene acetophenone-4-chlorobenzoyl hydrazone;Py=pyridine) with bacbh as ligand has been prepared from aqueous solution and characterized by elemental analysis,IR,X-ray single crystal diffraction and thermogravimetric analysis.The crystal belongs to the monoclinic system with space group P2(1)/n,with a=1.344 3(6) nm,b=2.471 7(12) nm,c=1.465 1(7) nm,β=98.47°,V=4.815(4) nm3,Z=4,μ=0.561 mm-1,Dc=1.292 mg/m3,F(000)=1 944,final R indicesI>2sigma(I)] R1=0.038 6,wR2=0.096 1(all data),GOF=1.007(CCDC:840865). |
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| Keywords: | hydrazone hydrothermal synthesis complex crystal structure thermal stability |
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