| 2,4,5-三硝基咪唑有机胺盐的合成与性能 |
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| 引用本文： | 杨威,于震坤,李亚南,廉鹏,王友兵,李辉,王伯周,叶志虎.2,4,5-三硝基咪唑有机胺盐的合成与性能[J].应用化工,2012,41(5):928-930. |
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| 作者姓名： | 杨威 于震坤 李亚南 廉鹏 王友兵 李辉 王伯周 叶志虎 |
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| 作者单位： | 1. 西安近代化学研究所,陕西西安,710065
2. 中国寰球工程公司,北京,100029 |
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| 摘 要： | 以2,4,5-三硝基咪唑(TNI)为原料,合成了TNI的胍盐(GTNI)、三氨基胍盐(TAGTNI)、脒基脲盐(GUTNI)等3种新化合物,并用红外光谱、核磁共振、元素分析等方法鉴定了结构。测试了GTNI、TAGTNI、GUTNI热安定性、密度与燃烧热,计算了生成焓与爆轰参数。结果表明,TAGTNI的生成焓和能量较高。
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| 关 键 词： | 2 4 5-三硝基咪唑胺盐 合成 性能 |
Synthesis and properties of 2,4,5-dinitroimidazole (TNI) salts |
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| YANG Wei
,
YU Zhen-kun
,
LI Ya-nan
,
LIAN Peng
,
WANG You-bing
,
LI Hui
,
WANG Bo-zhou
,
YE Zhi-hu.Synthesis and properties of 2,4,5-dinitroimidazole (TNI) salts[J].Applied chemical industry,2012,41(5):928-930. |
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| Authors: | YANG Wei YU Zhen-kun LI Ya-nan LIAN Peng WANG You-bing LI Hui WANG Bo-zhou YE Zhi-hu |
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| Affiliation: | 1(1.Xi’an Modern Chemistry Research Institute,Xi’an 710065,China; 2.China Huanqiu Contracting﹠Engineering Corp,Beijing 100029,China) |
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| Abstract: | Three new compounds of TNI,which were GTNI、TAGTNI and GUTNI,were synthesized with 2,4,5-TNI as raw materials.The structure of products were characterized by IR,NMR and elemental analysis,showing that the products were target products.The thermal stability,density and heat of combustion of GTNI,TAGTNI and GUTNI were tested.The enthalpy of formation and detonation parameters of products were calculated.The results showed that energy and the enthalpy of formation of TAGTNI was higher. |
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| Keywords: | TNI salts synthesis properties |
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