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甲醇在Fe/MgO、Co/MgO和Ni/MgO催化剂上裂解制备氢气
引用本文:朱刚,焦宝娟.甲醇在Fe/MgO、Co/MgO和Ni/MgO催化剂上裂解制备氢气[J].应用化工,2012,41(4):640-642.
作者姓名:朱刚  焦宝娟
作者单位:西安文理学院化学与化工系,陕西西安,710065
基金项目:陕西省教育厅资助项目,西安文理学院中青年科研基金项目
摘    要:采用浸渍法制备出3种MgO负载型过渡金属催化剂Fe/MgO、Co/MgO和Ni/MgO,系统研究了甲醇在3种催化剂上于600℃下的裂解产物。结果表明,3种催化剂均能催化甲醇裂解产生富氢气体,同时产生碳纳米管。其中,Ni/MgO具有最佳的催化效果。

关 键 词:甲醇  裂解  MgO负载型催化剂  氢气

Preparation of hydrogen by methanol decomposition over Fe/MgO, Co/MgO and Ni/MgO catalysts
ZHU Gang , JIAO Bao-juan.Preparation of hydrogen by methanol decomposition over Fe/MgO, Co/MgO and Ni/MgO catalysts[J].Applied chemical industry,2012,41(4):640-642.
Authors:ZHU Gang  JIAO Bao-juan
Affiliation:(Department of Chemistry and Chemical Engineering,Xi’an University of Arts and Science,Xi’an 710065,China)
Abstract:The catalysts of Fe,Co and Ni supported on MgO were prepared by the means of impregnation.Methanol decomposition over Fe/MgO,Co/MgO and Ni/MgO catalysts were systematically investigated at 600 ℃.The results indicated that the production of H2 by methanol decomposition could be realized over these catalysts and carbon nano-tubes were produced at the same time.Ni/MgO was the best one among the three catalysts.
Keywords:methanol  decomposition  supported MgO catalysts  hydrogen
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