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ABS增韧废PET饮料瓶片的性能与形态研究
引用本文:陈智军,王益龙,郑辰. ABS增韧废PET饮料瓶片的性能与形态研究[J]. 现代塑料加工应用, 2012, 24(1): 16-19
作者姓名:陈智军  王益龙  郑辰
作者单位:大连理工大学化工学院高分子材料系,辽宁大连,116024
摘    要:采用熔融挤出的方法研究了丙烯腈-丁二烯-苯乙烯共聚物(ABS)增韧废聚对苯二甲酸乙二醇酯(r-PET)饮料瓶片的力学性能和微观形态变化。结果表明,使用缩聚型反应挤出机对r-PET/ABS的混合效果优于使用双螺杆挤出机的,反应挤出机最佳螺筒温度为:245,260,255,255,240℃,最佳螺杆转速为80r/min;ABS质量分数为30%以下时,ABS以球状均匀地分散在r-PET连续相中;r-PET/ABS质量比为80/20的力学性能最佳,与r-PET相比,拉伸强度提高10 MPa,无缺口冲击强度提高6倍多,缺口冲击强度提高近l倍。

关 键 词:废聚对苯二甲酸乙二醇酯  饮料瓶片  丙烯腈-丁二烯-苯乙烯共聚物  反应挤出机  工程塑料  形态

Mechanical Properties and Morphology of Recycled PET Flakes Toughened by ABS
Chen Zhijun , Wang Yilong , Zheng Chen. Mechanical Properties and Morphology of Recycled PET Flakes Toughened by ABS[J]. Modern Plastics Processing and Applications, 2012, 24(1): 16-19
Authors:Chen Zhijun    Wang Yilong    Zheng Chen
Affiliation:Chen Zhijun Wang Yilong Zheng Chen(Department of Polymer Materials,Dalian University of Technology,Liaoning,Dalian,116024)
Abstract:Mechanical properties and morphology of recycled PET(r-PET) bottle flakes toughened by ABS were studied with melt extrusion.The experimental results indicate that reactive extruder is superior to twin-screw extruder in mixing effect;the optimum extrusion temperature is 245,260,255,255,240 ℃,and the optimum screw speed is 80 r/min;ABS disperses uniformly in r-PET continuous phase as spherical particle when its proportion is below 30%;the r-PET/ABS(80/20) shows the best mechanical properties in all,its tensile strength,non-notched impact strength and notched impact strength increase by 10 MPa,6 times,and near 1 time respectively compared with pure r-PET.
Keywords:recycled polyethylene terephthalate  bottle flakes  acrylonitrile-butadiene-styrene copolymer  reactive extruder  engineering plastics  morphology
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