| 二氧化碳与环氧烷加成反应的金属配合物催化剂及活化机理研究进展 |
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| 引用本文： | 王浩,刘定华,沈文彬,刘晓勤. 二氧化碳与环氧烷加成反应的金属配合物催化剂及活化机理研究进展[J]. 现代化工, 2011, 31(Z1): 51-56,58 |
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| 作者姓名： | 王浩 刘定华 沈文彬 刘晓勤 |
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| 作者单位： | 南京工业大学材料化学工程国家重点实验室,江苏南京210009;江苏省精细石油化工重点实验室,江苏常州213164 |
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| 基金项目： | 中国石油化工集团公司基金资助项目，江苏省精细石油化工重点实验室开放课题 |
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| 摘 要： | 综述了环氧烷与CO2开环加成反应合成环状碳酸酯的金属配合物催化剂的研究进展,讨论了金属配合物催化活化环氧烷和CO2完成环加成反应的活化机理,为CO2的化学利用及环氧烷合成环状碳酸酯工艺的研究、开发与应用提供参考。
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| 关 键 词： | 金属配合物 环氧乙烷 环氧丙烷 环状碳酸酯 二氧化碳 活化机理 |
Advances in metal complex catalysts and activation mechanism for addition reaction of epoxides with CO2 |
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| WANG Hao,LIU Ding-hua,SHEN Wen-bin,LIU Xiao-qin. Advances in metal complex catalysts and activation mechanism for addition reaction of epoxides with CO2[J]. Modern Chemical Industry, 2011, 31(Z1): 51-56,58 |
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| Authors: | WANG Hao LIU Ding-hua SHEN Wen-bin LIU Xiao-qin |
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| Affiliation: | WANG Hao1,2,LIU Ding-hua1,SHEN Wen-bin1,LIU Xiao-qin1,2(1.State Key Laboratory of Materials-Oriented Chemical Engineering,Nanjing University of Technology,Nanjing 210009,China,2.Jiangsu Key Laboratory of Fine Petrochemical Engineering,Changzhou 213164,China) |
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| Abstract: | The research progress in the metal complex catalysts for the synthesis of cyclic carbonate from epoxides with CO2 are summarized,and the activation mechanism of epoxides with CO2 for finishing the cycloaddition reaction are discussed systematically,which offers theoretical reference for carbon dioxide chemical utilization and the synthesis of cyclic carbonate form epoxides in technology research,development and application. |
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| Keywords: | metal complexes ethylene oxide propylene oxide cyclic carbonate carbon dioxide activation mechanism |
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