Polymerization via zwitterion. 23. Terpolymerization among 2-phenyl-1,3,2-dioxaphospholane,methyl acrylate,and carbon disulfide |
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| Authors: | Takeo Saegusa Jun-ichi Furukawa Yoshiharu Kimura Shiro Kobayashi |
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| Affiliation: | (1) Department of Synthetic Chemistry, Faculty of Engineering, Kyoto University, 606 Kyoto, Japan |
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| Abstract: | Summary The present paper describes the terpolymerization involving 2-phenyl-1,3,2-dioxaphospholane, methyl acrylate, and carbon disulfide, which took place without any added initiator in benzonitrile or dimethylformamide. The structure and composition of terpolymer were determined by NMR and IR spectra, as well as by elemental analysis. A reaction scheme proceeding via zwitterion  was proposed (Eq. 2–5). |
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