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Ternary diffusion formulation for diffusiophoresis
Authors:Joseph A Shaeiwitz  WJay Lechnick
Affiliation:Department of Chemical Engineering, University of Illinois, Urbana, IL 61801, U.S.A.
Abstract:A ternary diffusion formulation for diffusiophoresis, the migration of a particle in a solute gradient, is suggested. The formulation, derived from irr contributions in the D12 “cross-term” diffusivity. The ternary diffusion formulation allows both measurement of the magnitude of diffusioph transport situation. Measured coefficients of diffusiophoresis agree reasonably well with previous electrohydrodynamic theories.
Keywords:Author to whom correspondence should be addressed  
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