Temperature effects on separate values of adsorption and surface reaction rates by dynamic studies

The study of a three-phase catalytic slurry reactor for SO₂ oxidation on activated carbon has been conducted with a dynamic response technique. The analysis of zero and first temporal moments of the gas for temperatures between 10 and 26°C provides individual measurements of the adsorption, desorption and surface reaction rate constants and their energies of activation. A parallel first-moment analysis was carried out for O₂ adsorption onto carbon to obtain the necessary equilibrium constants for temperatures used in the SO₂-oxidation calculations. With second moment analysis of adsorption data, we find the adsorption kinetic constants with and without reaction are in quantitative agreement. By evaluating the separate temperatu effect on the adsorption/desorption, and surface reaction rates, we conclude that neither step is controlling at temperatures up to 26°C. The values the several kinetic and equilibrium constants agree well with those found by other authors.