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The diffusion coefficients of helium,hydrogen, oxygen and nitrogen in water determined from the permeability of a stagnant liquid layer in the quasi-s
Authors:PTHM Verhallen  LJP Oomen  AJJMvd Elsen  J Kruger  JMH Fortuin
Affiliation:Eindhoven University of Technology, Department of Physics, Den Dolech 2, 5612 AZ Eindhoven, The Netherlands;Department of Chemical Technology, University of Amsterdam The Netherland
Abstract:At temperatures between 10 and 60°C the diffusion coefficients of helium, hydrogen, oxygen and nitrogen in water have been determined from the permeability of a stagnant liquid layer in the quasi-steady state (SLL method). With this method we actually measure the difference in diffusive flow between two gases through a horizontal stagnant liquid layer between gas-permeable membranes. If oxygen is one of the gases, we are able to determine the diffusion coefficient of oxygen with a maximum experimental error of 3.5% and that of the other gases within 5%. Results are given and compared with experimental values stated in the literature.
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