| L-脯氨酸为阴离子的手性离子液体的合成、表征及光学活性 |
| |
| 引用本文： | 刘红霞,代剑飞,徐群. L-脯氨酸为阴离子的手性离子液体的合成、表征及光学活性[J]. 化学世界, 2012, 53(2): 108-110 |
| |
| 作者姓名： | 刘红霞 代剑飞 徐群 |
| |
| 作者单位： | 齐齐哈尔大学化学与化学工程学院,黑龙江齐齐哈尔,161006 |
| |
| 基金项目： | 黑龙江省教育厅2011年科学技术研究项目 |
| |
| 摘 要： | 以L-脯氨酸为手性源,合成了四种烷基咪唑手性离子液体,并进行了结构表征。烷基咪唑溴化物离子液体经与氢氧化钾碱化后再与氨基酸中和反应制得产物,探索了合适的反应条件。测定了产物的比旋光度,考察了各产物的光学纯度。
|
| 关 键 词： | L-脯氨酸 离子液体 合成 光学活性 |
Design and Synthesis of Chiral Ionic Liquids with L-Proline Anion and Their Optical Properties |
| |
| LIU Hong-xia , DAI Jian-fei , XU Qun. Design and Synthesis of Chiral Ionic Liquids with L-Proline Anion and Their Optical Properties[J]. Chemical World, 2012, 53(2): 108-110 |
| |
| Authors: | LIU Hong-xia DAI Jian-fei XU Qun |
| |
| Affiliation: | (College of Chemistry and Chemical Engineering,Qiqihar University,Heilongjiang Qiqihar 161006,China) |
| |
| Abstract: | A series of novel chiral alkyl imidazolium ionic liquids were synthesized from natural amino acids——L-proline.The structures of the target compounds were confirmed by ~1H NMR.Amino acids reacted with the intermediate of alkaline ionic liquids prepared from alkyl imidazolium bromide.Main factors affecting the conversion of the reactions were investigated.The optical rotation and purity of four kinds of ionic liquids were tested. |
| |
| Keywords: | L-proline ionic liquids synthesis optical activity |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
