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金属间化合物Sm_3(Fe_(1-x)V_x)_(29)的结构及其微观机制研究
引用本文:辛勇,罗广圣,雷宇,陈光. 金属间化合物Sm_3(Fe_(1-x)V_x)_(29)的结构及其微观机制研究[J]. 南昌大学学报(工科版), 2006, 0(4)
作者姓名:辛勇  罗广圣  雷宇  陈光
作者单位:南昌大学理学院,南昌大学材料科学与工程学院,南昌大学材料科学与工程学院,南昌大学科技学院 江西南昌330031
基金项目:江西省自然科学基金资助项目(0150014),南京大学固体微结构物理国家重点实施室开放基金项目(M041916)
摘    要:利用X射线衍射,金相显微镜,能谱分析以及差示扫描量热(DSC)等手段对金属间化合物Sm3(Fe1-xVx)29(x=0.01,0.03,0.05,0.08,0.1)的结构及其微观机制进行了研究.结果表明,金属间化合物Sm3(Fe1-xVx)29(x=0.01,0.03,0.05,0.08,0.1)的结构均为3:29型结构,并且随V含量增加,金属间化合物Sm3(Fe1-xVx)29的晶格常数和晶胞体积V均呈减少趋势.当x>0.05时,金属间化合物Sm3(Fe1-xVx)29中的杂质相明显呈现出来.随着V含量的增加,居里温度(TC)呈单调上升趋势.

关 键 词:金属间化合物  晶体结构  居里温度  杂质相  微观机制

The Study of Structure and Micro-mechanism of the Sm_3 (Fe_(1-x)V_x)_(29) Intermetallic Compounds
XIN Yonga,LUO Guang-shengb,LEI Yub,CHENG Guangc. The Study of Structure and Micro-mechanism of the Sm_3 (Fe_(1-x)V_x)_(29) Intermetallic Compounds[J]. Journal of Nanchang University(Engineering & Technology Edition), 2006, 0(4)
Authors:XIN Yonga  LUO Guang-shengb  LEI Yub  CHENG Guangc
Affiliation:XIN Yong~a,LUO Guang-sheng~b,LEI Yu~b,CHENG Guang~c
Abstract:The crystal strucuuse and micro-mechanism of the intermetallic compounds Sm_3(Fe_(1-x)V_x)_(29) were studied by X-Ray Diffraction,Metalloscope,EDS and Differential Scanning Calorimetry(DSC) methods etc.The following conclusion can be obtained: All the intermetallic compounds Sm_3(Fe_(1-x)V_x)_(29) compounds crystallize in (R_3(Fe,M)_(29)) type structure.The lattice parameters and the unit-cell volume V all decrease with the increase of V atom content x.The impurity phase was exhibited obviously as x>0.05.Curie temperature Tc increases monotonicly with V atom content.
Keywords:intermetallic compounds  Sm_3(Fe_(1-x)V_x)_(29)  crystal structure  Curie temperature  impurity phase  micro-mechanism
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