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Enhancement in electrical conductivity of Li2O: B2O3: V2O5 glasses
Authors:R. S. Gedam  V. K. Deshpande
Affiliation:(1) Department of Applied Physics, Visvesvaraya National Institute of Technology, Nagpur, 440 010, India
Abstract:The study of electrical conductivity of 30Li2O: (70 − x) B2O3: xV2O5 glass samples has been carried out. The results have been explained by dividing the temperature range into two regions. In region I, conductivity shows Arrhenius behaviour for all the samples. The conductivity increases with addition of V2O5. The results have been explained in the light of Anderson and Stuart Model. In region II, an anomalous enhancement in the conductivity is observed for all the samples up to certain temperature beyond which the conductivity decreases. The enhancement in the conductivity in the annealed glass sample has been attributed to nanocrystallization.
Keywords:Lithium conducting glasses  electrical conductivity  nucleation and crystallization  glass transition temperature
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