Corrosion behavior of Zr?Nb alloys in 360°C water and 500°C supercritical water |
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Authors: | Jeong-Yong Park Hyun-Gil Kim Yong Hwan Jeong |
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Affiliation: | (1) Advanced Core Materials Lab., Korea Atomic Energy Research Institute, 150, Deokjin-dong, Yuseong-gu, 305-353 Saejeon, Korea |
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Abstract: | The corrosion behavior of Zr−0.4 wt.%Nb and Zr−1.5 wt.%Nb alloys was investigated in 360°C water and 500°C supercritical water.
The two Zr−Nb alloys showed a similar corrosion rate in both corrosion conditions. However, in the 500°C supercritical water,
the corrosion rate was increased by 23 times when compared to that of the 360°C water based on the weight gain at 240 days.
In terms of the relationship between the corrosion and the precipitate characteristic, the β−Nb precipitates in the Zr−Nb
alloys were considered to play an important role in the excellent corrosion resistance in the 360°C water, but its beneficial
effect was not maintained in the 500°C supercritical water. The oxide characterization revealed that the tetragonal phase
stability was more easily decreased from the interface to the surface in the oxide formed in the 500°C supercritical water. |
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Keywords: | Zr alloys Corrosion Microstructure Oxide Supercritical water |
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