Synthesis, characterization, and electroluminescent properties of iridium complex containing 4-phenybenzoquinoline ligand |
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| Authors: | Chunxiang Li Hung-Hsin Shih Xiaoqing Jiang Peipei Sun Yi Pan Chien-Hong Cheng |
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| Affiliation: | aCollege of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, 266042, PR China;bJiangsu Key Laboratory of Biofunctional Materials, College of Chemistry and Environmental Science, Nanjing Normal University, Nanjing, 210097, PR China;cSchool of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, PR China;dDepartment of Chemistry, Tsing Hua University, Hsinchu, 300, Taiwan |
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| Abstract: | A phosphorescent iridium(III) complex Ir(PBQ)2(acac) (PBQ: 4-phenylbenzoquinoline, acac: acetylacetone) was designed and synthesized, and the single crystal of this complex was obtained. This complex shows well optoelectronic properties. The organic light emitting devices (OLEDs) based on this complex were successfully fabricated with the device configuration of ITO/NPB or TCTA (40 nm)/Ir-complex: CBP (7%, 30 nm)/BCP (15 nm)/Alq (30 nm)/LiF (1 nm)/Al (100 nm). Using TCTA as the hole-transporting material, the device gives an extremely high external quantum efficiency of 14.6% at 5.0 V, a brightness of 61,693 cd/m2 at 16.0 V, and a power efficiency of 37.0 lm/W at 3.5 V. |
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| Keywords: | Electrophosphorescence Ir-complex Synthesis OLEDs |
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