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Nanohybrid polymer prepared by successive polymerization of methacrylate monomer containing silver nanoparticles in situ prepared under microwave irradiation
Authors:Yuji Wada  Taishi Kobayashi  Takao Sakata  Hirotaro Mori
Affiliation:a Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita, Osaka 565-0871, Japan
b Department of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushima-Naka, Okayama 700-8530, Japan
c Nippon Shokubai Co., Ltd., 5-8 Nishi Otabi-cho, Suita, Osaka 564-8512, Japan
d Research Center for Ultra-High Voltage Electron Microscopy, Osaka University, 7-1 Mihogaoka, Ibaraki, Osaka 567-0047, Japan
Abstract:The well-dispersed silver nanoparticles were prepared in reactive methacrylate monomers under microwave irradiation without polymerization. In contrast to conventional heating, the synthesis of Ag nanoparticles proceeded uniformly throughout the reaction vessel only under microwave irradiation, reaching the completion of the reaction simultaneously in the whole reaction solution. Successive polymerization of the monomer containing the resulting nanoparticles has successfully produced a monohybrid of the silver nanoparticles dispersed in polymer matrix.
Keywords:Microwave   Nanohybrid   Silver nanoparticles
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