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Lateral habits ofn-alkane single crystals
Authors:A Toda  H Miyaji  Y Ogawa  K Takamizawa
Affiliation:(1) Department of Physics, Faculty of Science, Kyoto University, 606 Kyoto, Japan;(2) Faculty of General Education, Kumamoto University, 860 Kumamoto, Japan;(3) Department of Applied Science, Faculty of Engineering, Kyushu University, 812 Fukuoka, Japan
Abstract:The lateral crystal habits ofn-alkanes (n-C n H2n+2) have been observed just below the melting points by optical microscopy forn=18, 19, 20, 22, 24, 34, 44, 50 and 65. The shape of the crystals depends on the crystal phase: circular in the rotator phase, lenticular in phase C, and diamond in the low-temperature phase. The rounding of the lateral shape can be explained in terms of thermal roughening of the lateral faces in the disordered phases at high temperature.
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