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Preparation and characterization of porous acrylate terpolymer nanocomposite for removal of diesel oil from artificial seawater
Authors:N. A. Abdelwahab  F. M. Helaly
Affiliation:Department of Polymers and Pigments, National Research Centre, Dokki, Giza, Egypt
Abstract:The present work deals with the preparation of magnetic acrylate terpolymer nanocomposite by emulsion polymerization. This nanocomposite was applied for the removal of diesel oil from artificial seawater by magnetic separation. Magnetic terpolymer nanocomposite was characterized by Fourier transform infrared (FTIR) spectra, X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Specific surface area and pore size distribution were measured by the Brunauer–Emmett–Teller (BET) method. Contact angle (CA) measurement showed superhydrophobic properties of magnetic acrylate nanocomposite. Kinetics and isothermal studies indicate that oil sorption fits the second-order kinetic model and the Langmuir isotherm. Magnetic acrylate terpolymer can be regenerated for six cycles.
Keywords:Kinetics  magnetic  oil separation  porous acrylate terpolymer  recyclability
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