Sorption isotherms of metal ions onto an N-(2-sulfoethyl)chitosan-based material from single- and multi-component solutions |
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Authors: | Yulia S Petrova Elena I Kapitanova Ludmila K Neudachina Alexandr V Pestov |
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Affiliation: | 1. Ural Federal University Named After the First President of Russia B. N. Yeltsin, Institute of Natural Sciences and Mathematics, Yekaterinburg, Russia;2. I. Ya. Postovsky Institute of Organic Synthesis, Ural Division of Russian Academy of Sciences, Yekaterinburg, Russia |
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Abstract: | The scope of work is to study the mutual influence of metal ions during their sorption by sulfoethylated chitosan. The sorption isotherms of metal ions from single- and multi-component solutions are obtained. The sorption capacity of the sorbent towards Ag(I) and Cu(II) is revealed to be 1.63 and 1.41 mmol/g in single-, and 1.40 and 0.85 mmol/g in five-component solution. By comparing the affinity parameter and capacity of sulfoethylated chitosan towards ions in single- and multi-component solutions, it is concluded that Ag(I) and Cu(II) ions suppress the sorption of cobalt(II), nickel(II), zinc(II), cadmium(II), magnesium(II), calcium(II), strontium(II), barium(II), manganese(II) and lead(II). |
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Keywords: | Chitosan sorption isotherms sulfoderivatives |
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