Synthesis and crystal structures of copper(I) iodide complexes chelating with bis(ethylamidophosphine) |
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| Authors: | Yat Li Ka-Fu Yung Hoi-Shan Chan Wing-Tak Wong |
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| Affiliation: | aDepartment of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, PR China |
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| Abstract: | Two copper(I) iodide complexes with polydentate bis(ethylamidophosphine) ligands were synthesized, characterized with crystal structures. They include a dimeric complex [Cu(μ-I)(CH2NHCOC2H4PPh2)2]2 1 containing a planar Cu2I2 rhombohedron with two doubly bridged ligands and a tetrameric complex {Cu4(μ-I)4[(CH2NHCOC2H4PPh2)2]2} 3 with all the coppers and iodines forming a highly distorted cubane geometry. |
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| Keywords: | Copper(I) iodide complex Bis(ethylamidophosphine) Cubane Crystal structure |
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