Growth and properties of Hg1-xCdxTe on GaAs,with x − 0.27

The organometallic vapor phase epitaxy of HgCdTe onto (100)2°-(110) GaAs substrates is described in this paper. A buffer layer of CdTe has been grown prior to the growth of HgCdTe, to take up the large lattice mismatch with the GaAs. Considerations for the thickness of this buffer layer are outlined, and it is shown by quantitative Secondary Ion Mass Spectroscopy that there is negligible diffusion of gallium from the GaAs substrate for the growth conditions described. Hall effect measurements give mobilities comparable to those reported for bulk grown crystals. An extrinsicn-type carrier concentration of 2 × 10¹⁶/cm³ is obtained, and is mainly due to residual impurities in the starting chemicals. The alloy composition has been determined at 298 K by Fourier transform infrared transmission (FTIR) spectrometry; this is found to be extremely uniform over a 15 × 7 mm area, as evidenced by an overlapping of FTIR plots taken over this area. HgCdTe layers have been grown on buffer layers varying in thickness from 0.1 to 1.9μm. It is found that a buffer thickness of about 1.9μm or larger is required to obtain high quality HgCdTe, both in terms of the electrical characteristics (mobility and carrier concentration) and the infrared transmission curves (peak transmission).