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丙烯酸酯对水性聚氨酯胶粘剂的改性研究
引用本文:项尚林,陈瑞珠,乔海霞. 丙烯酸酯对水性聚氨酯胶粘剂的改性研究[J]. 粘接, 2006, 27(3): 12-14
作者姓名:项尚林  陈瑞珠  乔海霞
作者单位:南京工业大学材料科学与工程学院,江苏,南京,210009;南京工业大学材料科学与工程学院,江苏,南京,210009;南京工业大学材料科学与工程学院,江苏,南京,210009
摘    要:用自乳化的方法制备水性聚氨酯(PU)乳液,然后用丙烯酸酯进行改性,制备出水性聚氨酯和丙烯酸酯共聚乳液(PUA),并把聚丙烯酸酯(PA)乳液与PU乳液不同比例共混。考查了共聚型和共混型PUA乳液胶膜的吸水性、热行为、黏度、T型剥离强度。结果表明,在复合薄膜应用方面,共聚型PUA乳液的性能优于共混型PUA乳液。

关 键 词:水性聚氨酯乳液  聚丙烯酸酯乳液  共聚  共混  复合薄膜
文章编号:1001-5922(2006)03-0012-03
收稿时间:2005-10-07
修稿时间:2005-10-07

Study on aqueous polyurethane adhesive modified by acrylates for laminated films
XIANG Shang-lin,CHEN Rui-zhu,QIAO Hai-xia. Study on aqueous polyurethane adhesive modified by acrylates for laminated films[J]. Adhesion in China, 2006, 27(3): 12-14
Authors:XIANG Shang-lin  CHEN Rui-zhu  QIAO Hai-xia
Affiliation:College of Materials Science and Engineering, Nanjing University of Technology,Jiangsu Nanjing 210009, China
Abstract:In this article,a kind of aqueous polyurethane emulsion was synthesized by the way of self-emulsification,then modified with acrylate monomers or polyacrylate emulsions to get copolymer polyurethane-polyacrylate(PUA) emulsions or blend PUA emulsions.The hygroscopicity,T_g,viscosity and T-style peel strength of the films made with copolymer PUA and blend PUA were studied.It was found that the properties of copolymer PUA were super to that blend PUA in the applications of laminated films.
Keywords:aqueous polyurethane emulsion  polyacrylate emulsions  copolymerization  blending  laminated films
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