Effect of preadsorbed background organic matter on granular activated carbon adsorption of atrazine |
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Authors: | GS Wang KT Alben |
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Affiliation: | Department of Environmental Health and Toxicology, State University of New York at Albany, USA. gswang@ha.mc.ntu.edu.tw |
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Abstract: | This study examines the effect of preadsorbed background organic matter (measured as dissolved organic carbon, DOC) on the granular activated carbon (GAC) adsorption of atrazine. Thirty-four experiments were conducted in batch contactors using organic-free laboratory water (< 0.1 mg/l DOC) and pilot-column GAC, preloaded with DOC for 3-20 weeks (equivalent to 4.3-32 mg DOC/g GAC). Freundlich isotherms were determined for adsorption of atrazine at initial concentrations from 10 to 1000 micrograms/l. The isotherm data indicate that GAC capacities for atrazine are only moderately reduced by preadsorbed DOC. At an initial concentration of 1000 micrograms/l atrazine, the GAC capacity for atrazine decreases by -1.0 mg atz/mg preadsorbed DOC. At an initial concentration of 10 micrograms/l atrazine, the GAC capacity for atrazine decreases by only -0.40 mg atz/mg preadsorbed DOC. For the pilot-column GAC preloaded with a maximum of 32 mg DOC/g GAC, the decrease in capacity for atrazine averages -33 +/- 13%. |
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