Impact of Ni Content on the Structure and Sonophotocatalytic Activity of Ni-Zn-Co Ferrite Nanoparticles

The structure, morphology, and sonophotocatalytic activity of Ni-Zn-Co ferrite nanoparticles, embedded in a SiO₂ matrix and produced by a modified sol-gel method, followed by thermal treatment, were investigated. The thermal analysis confirmed the formation of metal succinate precursors up to 200 °C, their decomposition to metal oxides and the formation of Ni-Zn-Co ferrites up to 500 °C. The crystalline phases, crystallite size and lattice parameter were determined based on X-ray diffraction patterns. Transmission electron microscopy revealed the shape, size, and distribution pattern of the ferrite nanoparticles. The particle sizes ranged between 34 and 40 nm. All the samples showed optical responses in the visible range. The best sonophotocatalytic activity against the rhodamine B solution under visible irradiation was obtained for Ni_0.3Zn_0.3Co_0.4Fe₂O₄@SiO₂.