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High efficiency, solution-processed, red phosphorescent organic light-emitting diodes from a polymer doped with iridium complexes
Authors:Myungkwan Song   Jin Su Park   Chul-Hyun Kim   Min Joung Im   Jang Soo Kim   Yeong-Soon Gal   Jae-Wook Kang   Jae Wook Lee  Sung-Ho Jin  
Affiliation:1. Department of Chemistry Education, Interdisciplinary Program of Advanced Information and Display Materials, and Center for Plastic Information System, Pusan National University, Busan 609-735, Republic of Korea;2. Polymer Chemistry Lab., Kyungil University, Hayang 712-701, Republic of Korea;3. Department of Surface Technology, Korea Institute of Materials Sciences, Changwon 641-831, Republic of Korea;4. Department of Chemistry, Dong-A University, Busan 604-714, Republic of Korea
Abstract:High efficiency, solution-processed, red emissive phosphorescent organic light-emitting diodes (PhOLEDs) have been developed. The PhOLEDs utilize bis[9-ethyl-3-(4-phenylquinolin-2-yl)-9H-carbazolato-N,C2′]iridium picolinate (Et-Cvz-PhQ)2Ir(pic) and bis[9-(2-(2-methoxyethoxy)ethyl)-3-(4-phenylquinolin-2-yl)-9H-carbazolato-N,C2′]iridium picolinate (EO-Cvz-PhQ)2Ir(pic) in a nonconjugated polymer host of PVK that contains the electron transport material of OXD-7 and the hole transport material TPD. The electroluminescence (EL) spectra of the PhOLEDs parallel those of (Et-Cvz-PhQ)2Ir(pic) and (EO-Cvz-PhQ)2Ir(pic) with maxima at 608 nm and a CIE (Commission International de l’Eclairage) coordinate of (0.62, 0.38). The red emitting PhOLEDs, based on ITO/PEDOT:PSS/PVK:OXD-7:TPD:Ir complex/cathode configuration, have a maximum external quantum efficiency of 10.6% and a luminance efficiency of 17.5 cd/A. The efficiency is significantly higher than those obtained using common solution-processed red emissive PhOLEDs.
Keywords:Solution-process   PhOLEDs   Phosphorescent   Red   Hole transporting material
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