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聚硅酸钙铝混凝剂处理造纸中段废水
引用本文:张万友,武倩,金立忠,邬永成,徐晓春.聚硅酸钙铝混凝剂处理造纸中段废水[J].中华纸业,2011,32(22):59-62.
作者姓名:张万友  武倩  金立忠  邬永成  徐晓春
作者单位:1. 东北电力大学化学工程学院,吉林省吉林市,132012
2. 大唐长春第二热电有限责任公司,长春,132010
摘    要:以电石渣、硅酸钠、硫酸铝、浓硫酸为原料制备了一种高效复合混凝剂聚硅酸钙铝(PACSs),并将其应用于造纸中段废水的处理。研究了加药量、PH值、沉降时间三个因素对PACSS处理造纸中段废水混凝效果的影响。研究结果表明:PACSs在加药量为57.5mg/L、PH值为7.0、沉降时间为35min的条件下,浊度、CODCr,和色度的去除率分别为96.8%,82.8%、96.4%。与传统混凝剂硫酸铝(AS)和聚合氯化铝(PAC)相比,其处理造纸中段废水的效果具有明显的优势。

关 键 词:聚硅酸钙铝  电石渣  中段废水  混凝效果

Studies on washing & bleaching effluent treatmentwith poly-aluminum-calcium-silicate sulfate
ZHANG Wan-you,WU Qian,JIN Li-zhong,WU Yong-cheng,XUXiao-chun.Studies on washing & bleaching effluent treatmentwith poly-aluminum-calcium-silicate sulfate[J].China Pulp & Paper Industry,2011,32(22):59-62.
Authors:ZHANG Wan-you  WU Qian  JIN Li-zhong  WU Yong-cheng  XUXiao-chun
Affiliation:1.School of Chemical Engineering, Northeast Dianli University, Jilin 132012, Jilin, China; 2.Chemical Department of Datang Changchun Second Thermal Power Co. Ltd., Changchun 132010, China)
Abstract:The poly-aluminum-calcium-silicate sulfate (PACSS) coagulant is a new efficient composite coagulant which was prepared by carbide slag, sodium silicate, aluminum sulfate, and concentrated sulfuric acid. It was applied to the treatment of washing and bleaching effluent in paper mills. The influence of PACSS coagulant dosage, pH value and sedimentation time on the coagulation was examined. The results show that PACSS can reach a better results in the treatment of washing and bleaching effluent than AS and PAC. The optimal treating condition are as follow: PACSS dosage 37.5mg/ L, pH value 7.0 and sedimentation time 35 minutes, under which conditions the removal rates of the turbidity, CODCr and chroma can reach 96.8%, 82.8%, 96.4% respectively. It proved that PACSS coagulant is superior to conventional coagulant PAC and AS in the treatment of washing and bleaching effluent in paper mills.
Keywords:PACSS  carbide slag  washing & bleaching effluent  coagulation
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