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采用高吸水树脂为模板制备新型纳米炭材料的研究
引用本文:王海旺,赵天波,缪策,魏新芳,张帅,宋怀河.采用高吸水树脂为模板制备新型纳米炭材料的研究[J].炭素,2011(3):3-7.
作者姓名:王海旺  赵天波  缪策  魏新芳  张帅  宋怀河
作者单位:1. 北京理工大学原子分子簇科学教育部重点实验室,北京,100081
2. 北京化工大学化工资源有效利用国家重点实验室,北京,100029
基金项目:高等学校学科创新引智计划资助(B07012)111Project(B07012)国家自然科学基金资助(20973022)Supported by the National Natural Science Foundation of China(No.20973022)
摘    要:首先采用高吸水树脂为模板,制备了四重网络结构高吸水树脂,然后采用四重高吸水树脂为有机模板,蔗糖为炭源制备了新型纳米炭材料,研究了四重高吸水树脂的高分子网络结构及蔗糖溶液的浓度对新型纳米炭材料微观结构的影响。研究结果表明:采用四重高吸水树脂为模板可以制备出新型纳米炭颗粒,这些纳米炭颗粒可以自组装成不同的微观形貌。XRD和Raman的研究结果表明,蔗糖的浓度对新型炭材料的微观结构也有较大的影响。

关 键 词:高吸水树脂  炭材料  纳米结构

STUDY ON THE PREPARATION OF NEW NANOSTRUCTURED CARBON MATERIALS USING SUPERABSORBENT POLYMER AS A TEMPLATE
Wang Hai-wang,Zhao Tian-bo,Miao Ce,Wei Xin-fang,Zhang Shuai,Song Huai-he.STUDY ON THE PREPARATION OF NEW NANOSTRUCTURED CARBON MATERIALS USING SUPERABSORBENT POLYMER AS A TEMPLATE[J].Carbon,2011(3):3-7.
Authors:Wang Hai-wang  Zhao Tian-bo  Miao Ce  Wei Xin-fang  Zhang Shuai  Song Huai-he
Affiliation:Wang Hai -wang, Zhao Tian - bo, Miao Ce, Wei Xin - fang, Zhang Shuai, Song Huai - he (1.Beijing Institute of Technology,Key Laboratory of Cluster Science of Ministry of Education,Beijing 100081, P. R China; 2. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R China)
Abstract:Superabsorbent polymer with fourfold polymer network was prepared for the first time using a superabsorbent polymer as a template. And then new nanostructured carbon materials were prepared using the superabsorbent polymer with fourfold polymer network as an organic template and sucrose as a carbon precur- sor.The influence of the polymer networks of the superabsorbent polymer on the microstructures of the car- bons was studied.The results show that nanostructured spherical carbons could be prepared using superabsorbent polymer with fourfold polymer network as a template, and these nanostructured spherical car- bons self- assembled into distinct morphologies.The results of XRD and Raman show that concentration of the sucrose solution influenced the microstructure of the nanostructured carbon materials greatly as well.
Keywords:superabsorbent polymer  carbon material  nanostructured
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