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| CO_2加氢合成甲醇CuO-ZnO-TiO_2催化剂的制备与表征 | |
| 引用本文： | 赵云鹏,贾丽华,孙德智,郑钟植.CO_2加氢合成甲醇CuO-ZnO-TiO_2催化剂的制备与表征[J].天然气化工,2011,36(5). |
| 作者姓名： | 赵云鹏 贾丽华 孙德智 郑钟植 |
| 作者单位： | 1. 哈尔滨工业大学市政环境工程学院,黑龙江哈尔滨150090;齐齐哈尔大学化学与化学工程学院,黑龙江齐齐哈尔161006 2. 齐齐哈尔大学化学与化学工程学院,黑龙江齐齐哈尔,161006 3. 哈尔滨工业大学市政环境工程学院,黑龙江哈尔滨150090;北京林业大学环境科学与工程学院,北京100083 4. 哈尔滨工业大学市政环境工程学院,黑龙江哈尔滨150090;浦项工科大学环境工程学院,韩国庆尚北浦项790-784 |
| 基金项目： | 齐齐哈尔大学青年教师科研启动支持计划重点项目，齐齐哈尔市科技计划工业攻关重点项目 |
| 摘 要： | 采用添加表面活性剂并流浆态沉淀法制备了CuO-ZnO-TiO2催化剂,利用N2吸附脱附、XRD、SEM、EDS和H2-TPR等方法对催化剂进行了表征。结果表明,CuO-ZnO-TiO2催化剂为平均孔径3.7436nm的介孔材料,CuO在催化剂上的分散性较好,还原温度较低。在反应温度230℃、反应压力2.0MPa、反应空速2100h-1、H2和CO2摩尔比为3:1的条件下,CO2加氢合成甲醇效果较好,甲醇选择性为19.68%,甲醇产率为2.26%。 |
| 关 键 词： | CuO-ZnO-TiO2催化剂 二氧化碳加氢 甲醇合成 并流浆态沉淀法 表面活性剂 |
Preparation and characterization of CuO-ZnO-TiO2 catalyst for methanol synthesis from carbon dioxide hydrogenation |
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| ZHAO Yun-peng,JIA Li-hua,Sun De-zhi,Chung Jong-shik.Preparation and characterization of CuO-ZnO-TiO2 catalyst for methanol synthesis from carbon dioxide hydrogenation[J].Natural Gas Chemical Industry,2011,36(5). | |
| Authors: | ZHAO Yun-peng JIA Li-hua Sun De-zhi Chung Jong-shik |
| Abstract: | The CuO-ZnO-TiO2 catalyst was prepared by parallel-slurry-mixing-precipitation method combined with addition of surfactant and characterized by nitrogen adsorption-desorption,XRD,SEM,EDS and H2-TPR.The results showed that the average pore diameter of the mesoporous CuO-ZnO-TiO2 catalyst was 3.7436 nm,and the dispersion of CuO was good on CuO-ZnO-TiO2 catalyst and the reduction temperature of CuO was low.Under the conditions of reaction temperature of 230℃,reaction pressure of 2.0MPa,space velocity of 2100h-1 and feed gas H2/CO2 molar ratio of 3:1,methanol synthesis from CO2 hydrogenation obtained optimal results,giving a selectivity to methanol of 19.68% and a methanol yield of 2.26%. |
| Keywords: | CuO-ZnO-TiO2 catalyst carbon dioxide hydrogenation methanol synthesis parallel-slurry-mixing-precipitation surfactant |
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