Nucleation and growth modes deduced from particle density distributions: Nanocrystallization of fcc Al in amorphous Al85Ni8Y5Co2 |
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Authors: | Heiko Nitsche Ferdinand Sommer Eric Jan Mittemeijer |
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Affiliation: | (1) the Max Planck Institute for Metals Research, Germany;(2) Robert Bosch GmbH, D-72703 Reutlingen, Germany;(3) Max Planck Institute for Metals Research, D-70569 Stuttgart, Germany;(4) the Max Planck Institute for Metals Research, D-70569 Stuttgart, Germany;(5) the Institute of Physical Metallurgy, University of Stuttgart, D-70569 Stuttgart, Germany |
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Abstract: | A general model to simulate the particle density distribution of a product phase upon phase transformation has been developed
in a modular way. In particular, the influence of different nucleation and growth mechanisms known from solid-state phase
transformations on the shape of the product phase particle density distribution has been investigated. The model has been
fitted to experimental particle density distributions of nanoparticles of fcc Al developing in amorphous Al85Ni8Y5Co2 upon annealing for different times (1 minute to 2 hours) at various temperatures (473 to 508 K). Transient nucleation at
a limited number of favored nucleation sites in combination with a two-stage growth mechanism (interface-controlled growth
in the beginning and volume diffusion-controlled growth in the subsequent growth stage) very well describes the nanocrystallization
process of amorphous Al85Ni8Y5Co2. |
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Keywords: | |
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