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Improved Aging Characteristics of NTC Thermistor Thin Films Fabricated by a Hybrid Sol–Gel–MOD Process
Authors:Dmitry A. Kukuruznyak  Jerome G. Moyer   Fumio S. Ohuchi
Affiliation:Department of Materials Science and Engineering, University of Washington, Seattle, Washington 98195
Abstract:Negative temperature coefficient thermistor oxide thin films with improved aging characteristics are described. Better thermal stability has been achieved by incorporating sol–gel techniques with metallo-organic decomposition methods. A compositional range was identified whereby borosilicate may incorporate into the thermistor oxides, forming nanocomposites showing thermistor electrical characteristics. Thermistor thin films, with composition Ni0.48Co0.24Cu0.6Mn1.68O4·0.22SiO2·0.15B2O3 were deposited onto glass substrates from a solution containing organic transition metal salts, tetraethyl orthosilicate and triethyl borate. Electrical resistance measurements verified characteristic thermistor behavior. Nanocomposite thin films exhibited a factor of four improvement as compared with pure oxides after aging at 150°C for 500 h.
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